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By Shigeyuki Somiya (Eds.)

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828). 2 . Silicification of carbon (direct reaction between silicon and c a r b o n ) : P o w d e r e d silicon and a carbon source such as carbon black are m a d e to react directly at a comparatively low t e m p e r a t u r e , as given in the following formula ( H a s e and Suzuki, 1978, pp. 5 4 1 , 606): Si + C SiC 3. Gas-phase reaction, gas-phase pyrolysis: Gases such as SiCl or S i H are m a d e to react with hydrocarbons, or gases such as C H S i C l or ( C H ) S i are m a d e to undergo pyrolysis, yielding a fine p o w d e r .

97). 4 3 3 2 4 3 These m e t h o d s produce an extremely fine p o w d e r with a higher degree of purity than do those discussed earlier, but there are many peripheral problems with the technology, such as m e a n s of preventing oxidation during handling of these powders and of forming good green compacts; these aspects must be improved in the future. T h e cost of the initial materials is high, but, as chemical processes, they also have r o o m for cost 3. Synthetic Raw Materials for Ceramics 59 reduction through mass production.

1980). S i H - C H - H kei kisö hannö ni yoru tankakeiso funtai no gösei [Synthesis of silicon carbide powders by a S i H - C H - H vapor phase reaction]. Nippon kagaku kaishi, 188-193. Scott, H. G. (1975). Phase relations in the zirconia-yttria system. Journal of Materials Science, 10, 1527-1535. Takamiya, Yöichi. (1982). Magunesia [Synthetic magnesia]. Ceramics Japan, 17, 823-828. ). (1979). Seramikkusu no kikaiteki seishitsu [Mechanical properties of ceramics]. Tokyo: Y ö g y ö Kyökai.

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